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Use of Zircon in the Physicochemical Process of Defluorination of Hyperfluorinated Brackish Water from the Diouroup Borehole (Senegal)

Received: 1 June 2024     Accepted: 17 June 2024     Published: 2 July 2024
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Abstract

In phosphate-producing countries (United States, Commonwealth of Independent States, North and West Africa including Senegal), the presence of phosphate ores (hydroxyapatite) is often associated with that of fluorine ores (fluoro apatite). In these regions, water from confined aquifers may have excessive fluoride contents. While the potability standards in tropical climates are 0.7 mg/L at a temperature of 25°C In the central zone of Senegal, hyperfluorinated brackish water constitutes a public health problem. It is in this context that it was decided to make our contribution to the purification of drinking water in this area. In our study, we used as an element in the physicochemical defluorination process. The results obtained, by this physicochemical treatment by filtration on the zircon column, showed overall a reduction in fluoride contents of 67.55% (i.e. from 6.41 mg/L to 2.08 mg/L) in chlorides of 10.44%. We can therefore affirm that zircon can be used for the defluorination of hyperfluorinated brackish waters. However, these results can be improved by lowering the pH of the water before treatment and increasing the retention time.

Published in Science Journal of Chemistry (Volume 12, Issue 4)
DOI 10.11648/j.sjc.20241204.11
Page(s) 63-72
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Zircon, Defluorination, Adsorption, Brackish Water, Diouroup

References
[1] Y. TRAVI, “Hydrogeochemistry and isotopic hydrology of fluoride aquifers in the Senegal basin: origin and transport conditions of fluoride in groundwater.,” Paris, 1988.
[2] MHZAYM and DEHGHANI, “Fluoride contamination in groundwater resources in the southern Iran and its related human health risks,” Desalin. Water Treat, vol. 153, p. 95-104, 2019.
[3] MLXHW-yea WANG, “Distribution, health risk assessment, and anthropogenic sources of fluoride in farmland soils in phosphate industrial area, southwest China,” Environmental Pollution, vol. 249, pp. 423-433, 2019.
[4] CSNAFA RABIER, “Epidemiological study: impact of fluoride ingested via drinking water on the health of the populations of five rural communities in Senegal Epidemiological study: impact of fluorides.,” Journal of Sciences and Technology, vol. 7, no.%12, pp. 7-12, 2008.
[5] A. LY, D. GASSAMA and B. NGOM, “Study and Proposal for a Hyperfluorinated Brackish Water Treatment System in the Fatick Region, Case of Diouroup (Senegal),” American Journal of Analytical Chemistry, vol. 12, no.%111, pp. 392-407, 2021.
[6] MRMNM and aa PONTIÉ, “On the problem of fluorosis in Senegal: Review of knowledge and presentation of a new one.,” Cahiers santé, vol. 6, pp. 27-36, 1996.
[7] Y. TRAVI, “Hydrogeology and hydrochemistry of the aquifers of Senegal. Hydrogeochemistry of fluorine in groundwater.,” Persée-Portal of scientific journals in SHS, 1993.
[8] YAPO N'ZÉBO SYLVESTRE, Defluoridation of drinking water by adsorption-precipitation on doctoral thesis, Abidjan: INSTITUT NATIONAL POLYTECHNIQUE FELIX HOUPHOUËT-BOIGNY, 2022.
[9] YWXZL and GAN, “Coagulation removal of fluoride by zirconium tetrachloride: performance evaluation and mechanism analysis,” Chemosphere, vol. 218, p. 860-868., 2019.
[10] LHHRHMJ and VELAZQUEZ-JIMENEZ, “Zirconium–carbon hybrid sorbent for removal of fluoride from water: oxalic acid mediated Zr (IV) assembly and adsorption mechanism.,” Environmental science & technology, vol. 48, n°%1 2, pp. 1166-1174, 2014.
[11] M. Sane, “Notes on Senegal's Water Resources: Potential Areas for Water Transfer,” vol. 8, 2015.
[12] MN a. NV Antonysamy Jeyaseelan, “Development of Multivalent Metal-Ion-Fabricated Fumaric Acid-Based Metal−Organic Frameworks for De fl uoridation of Water,” Chemical and Engineering Data, vol. 65, p. 2990−3001, 2020.
[13] TCTSAJYAC and PANG, “Removal of fluoride from water activated using carbon fibers modified with zirconium by a drop-coating method.,” Chemosphere, Vols.%1 of%2255, p. 126950., 2020.
[14] MC Nko'o Abuiboto, J. Avom and R. Mpon, “Evaluation of the properties of activated carbons from Moabi (Baillonella toxisperma Pierre) residues by adsorption of iodine in aqueous solution,” Revue des sciences de l'eau, n°%1291, p. 51–60, 2016.
[15] O. mdl Santé, Drinking Water Quality Guidelines: 4th ed. Incorporating the first additive [Guidelines for drinking-water quality: 4th ed. Incorporating first addendum], 2017.
[16] J. Rodier, B. Legube and N. Merlet, Water analysis - Control and interpretation 10th edition, 2016.
[17] CD CE, “DIRECTIVE 98/83/ relating to the quality of water intended for human consumption,” 1998.
[18] ANM e. VN JEYASEELAN, “Development of multivalent metal-ion-fabricated fumaric acid-based metal–organic frameworks for defluoridation of water,” Journal of Chemical & Engineering Data, vol. 65, no.%16, pp. 2990-3001, 2020.
[19] MS Muthu Prabhu S, “Defluoridation of water using dicarboxylic acids mediated chitosan-polyaniline/zirconium biopolymeric complex,” International Journal of Biological Macromolecules, vol. 85, pp. 16-22, Apr 2016.
[20] SM e. MS PRABHU, “Novel one-pot synthesis of dicarboxylic acids mediated alginate–zirconium biopolymeric complex for defluoridation of water,” Carbohydrate polymers, vol. 120, pp. 60-68, 2015.
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Cite This Article
  • APA Style

    Ly, A., Coly, A. M., Camara, N., Ngom, B., Gassama, D., et al. (2024). Use of Zircon in the Physicochemical Process of Defluorination of Hyperfluorinated Brackish Water from the Diouroup Borehole (Senegal). Science Journal of Chemistry, 12(4), 63-72. https://doi.org/10.11648/j.sjc.20241204.11

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    ACS Style

    Ly, A.; Coly, A. M.; Camara, N.; Ngom, B.; Gassama, D., et al. Use of Zircon in the Physicochemical Process of Defluorination of Hyperfluorinated Brackish Water from the Diouroup Borehole (Senegal). Sci. J. Chem. 2024, 12(4), 63-72. doi: 10.11648/j.sjc.20241204.11

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    AMA Style

    Ly A, Coly AM, Camara N, Ngom B, Gassama D, et al. Use of Zircon in the Physicochemical Process of Defluorination of Hyperfluorinated Brackish Water from the Diouroup Borehole (Senegal). Sci J Chem. 2024;12(4):63-72. doi: 10.11648/j.sjc.20241204.11

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  • @article{10.11648/j.sjc.20241204.11,
      author = {Alioune Ly and Anabilaye Moussa Coly and Ndiouga Camara and Baba Ngom and Diadioly Gassama and Séni Tamba},
      title = {Use of Zircon in the Physicochemical Process of Defluorination of Hyperfluorinated Brackish Water from the Diouroup Borehole (Senegal)
    },
      journal = {Science Journal of Chemistry},
      volume = {12},
      number = {4},
      pages = {63-72},
      doi = {10.11648/j.sjc.20241204.11},
      url = {https://doi.org/10.11648/j.sjc.20241204.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20241204.11},
      abstract = {In phosphate-producing countries (United States, Commonwealth of Independent States, North and West Africa including Senegal), the presence of phosphate ores (hydroxyapatite) is often associated with that of fluorine ores (fluoro apatite). In these regions, water from confined aquifers may have excessive fluoride contents. While the potability standards in tropical climates are 0.7 mg/L at a temperature of 25°C In the central zone of Senegal, hyperfluorinated brackish water constitutes a public health problem. It is in this context that it was decided to make our contribution to the purification of drinking water in this area. In our study, we used as an element in the physicochemical defluorination process. The results obtained, by this physicochemical treatment by filtration on the zircon column, showed overall a reduction in fluoride contents of 67.55% (i.e. from 6.41 mg/L to 2.08 mg/L) in chlorides of 10.44%. We can therefore affirm that zircon can be used for the defluorination of hyperfluorinated brackish waters. However, these results can be improved by lowering the pH of the water before treatment and increasing the retention time.
    },
     year = {2024}
    }
    

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  • TY  - JOUR
    T1  - Use of Zircon in the Physicochemical Process of Defluorination of Hyperfluorinated Brackish Water from the Diouroup Borehole (Senegal)
    
    AU  - Alioune Ly
    AU  - Anabilaye Moussa Coly
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    AU  - Baba Ngom
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    JF  - Science Journal of Chemistry
    JO  - Science Journal of Chemistry
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    EP  - 72
    PB  - Science Publishing Group
    SN  - 2330-099X
    UR  - https://doi.org/10.11648/j.sjc.20241204.11
    AB  - In phosphate-producing countries (United States, Commonwealth of Independent States, North and West Africa including Senegal), the presence of phosphate ores (hydroxyapatite) is often associated with that of fluorine ores (fluoro apatite). In these regions, water from confined aquifers may have excessive fluoride contents. While the potability standards in tropical climates are 0.7 mg/L at a temperature of 25°C In the central zone of Senegal, hyperfluorinated brackish water constitutes a public health problem. It is in this context that it was decided to make our contribution to the purification of drinking water in this area. In our study, we used as an element in the physicochemical defluorination process. The results obtained, by this physicochemical treatment by filtration on the zircon column, showed overall a reduction in fluoride contents of 67.55% (i.e. from 6.41 mg/L to 2.08 mg/L) in chlorides of 10.44%. We can therefore affirm that zircon can be used for the defluorination of hyperfluorinated brackish waters. However, these results can be improved by lowering the pH of the water before treatment and increasing the retention time.
    
    VL  - 12
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Author Information
  • Department of Civil Engineering, Laboratoire des Sciences et Technologies de l'Eau et de l'Environnement, Ecole Polytechnique, Thiès, Sénégal

  • Department of Science and Technology, Iba Der Thiam University, Thies, Senegal

  • Department of Geotechnical, UFR Sciences de l’ingénieur, Iba Der Thiam University, Thies, Senegal

  • Departement of Common Core, Laboratory of Water and Environmental Sciences and Technologies, Thiès, Senegal

  • Department of Science and Technology, Iba Der Thiam University, Thies, Senegal

  • Department of Civil Engineering, Laboratoire des Sciences et Technologies de l'Eau et de l'Environnement, Ecole Polytechnique, Thiès, Sénégal

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